Add salt to ice and the ice melts, drawing the heat it needs from its surroundings, so the mixture falls below zero. The effect was in use in kitchens and laboratories long before mechanical refrigeration.
| Year | Record | What was done |
|---|---|---|
| 1718 | Mary Eales's book of receipts | Pots of cream buried in ice and bay salt and frozen in a cellar |
| 1724 | Fahrenheit, Philosophical Transactions | Zero on the thermometer marked with ice, water and sal ammoniac or sea salt |
However much salt is added, the temperature does not fall below a certain limit. For sodium chloride and water that limit is the eutectic point: about -21.2 °C at 23.2 percent salt by weight. GEBHARDT's salt-solution eutectic plates come in several melting points including -21 °C; the measured mixture sits in a sealed body, and the user only freezes the plate.

